Earth's Interior
PREM, seismic discontinuities, and the thermal structure of our planet
2.1 The Preliminary Reference Earth Model (PREM)
The Preliminary Reference Earth Model (PREM) by Dziewonski and Anderson (1981) is the standard 1D radial model of Earth's interior. It specifies density $\rho(r)$, P-wave velocity $V_P(r)$, S-wave velocity $V_S(r)$, and attenuation as functions of radius, constrained by body-wave travel times, surface wave dispersion, and normal mode frequencies.
Derivation 1: The Adams-Williamson Equation
The density distribution within Earth can be estimated from seismic velocities using the Adams-Williamson equation. Start with hydrostatic equilibrium:
The adiabatic bulk modulus relates pressure changes to density changes:
where the seismic parameter $\phi$ is directly measurable:
Combining hydrostatic equilibrium with the adiabatic equation of state:
This is the Adams-Williamson equation. Starting from the surface with known density and integrating inward, it yields the density profile. Deviations from the Adams-Williamson prediction indicate compositional changes or phase transitions.
Historical Context
The determination of Earth's internal structure is one of the great achievements of geophysics. Key milestones include: Wiechert (1897) proposed an iron core; Oldham (1906) identified the core seismologically; Gutenberg (1914) placed the core-mantle boundary at 2900 km; Lehmann (1936) discovered the inner core; Birch (1952) used the Adams-Williamson equation to constrain mantle composition; and Dziewonski and Anderson (1981) published PREM.
2.2 Seismic Discontinuities
Earth's interior contains several major discontinuities where seismic velocities change abruptly, indicating changes in composition or mineral phase:
- Moho (Mohorovicic, 1909): Crust-mantle boundary at ~7 km (oceanic) to ~35-70 km (continental). $V_P$ jumps from ~6.5 to ~8.1 km/s.
- 410 km discontinuity: Olivine to wadsleyite phase transition. $V_P$ increases by ~5%.
- 660 km discontinuity: Ringwoodite to bridgmanite + ferropericlase. Marks the base of the transition zone.
- D'' layer (~2700 km): A ~200 km thick heterogeneous region above the CMB with possible post-perovskite phase.
- Core-Mantle Boundary (2891 km): $V_P$ drops from ~13.7 to ~8.1 km/s; $V_S$ drops to zero.
- Inner Core Boundary (5150 km): $V_S$ reappears as liquid iron solidifies.
Derivation 2: Reflection Coefficient at a Discontinuity
When a seismic wave encounters a sharp velocity contrast, energy is reflected and transmitted. For normal incidence of a P-wave on an interface between media with impedances$Z_1 = \rho_1 V_{P1}$ and $Z_2 = \rho_2 V_{P2}$:
The transmission coefficient is:
The energy reflection coefficient is $R^2$, and energy conservation requires$R^2 + \frac{Z_2}{Z_1}T^2 = 1$. At the CMB, the large impedance contrast produces strong reflections (PcP, ScS phases), while at the Moho the contrast generates prominent reflected phases used in crustal studies.
2.3 Geothermal Gradient and Heat Flow
Derivation 3: Conductive Geotherm with Heat Production
In the continental crust, heat is produced by radioactive decay of U, Th, and K. The steady-state heat conduction equation with internal heat production $A$ is:
where $k$ is thermal conductivity and $z$ is depth (positive downward). If heat production decreases exponentially with depth, $A(z) = A_0 e^{-z/h_r}$ where$h_r$ is the characteristic depth (~10 km):
where $T_0$ is surface temperature and $q_m$ is the mantle heat flow (heat flux from below the radioactive layer). The surface heat flow is:
This is the Lachenbruch linear heat flow relation (1968): surface heat flow equals mantle heat flow plus the integrated crustal radiogenic contribution. Typical values are $q_0 = 60$-90 mW/m$^2$ for continents and $q_m \approx 20$-30 mW/m$^2$.
Derivation 4: Adiabatic Temperature Gradient in the Mantle
Below the lithosphere, heat transport is dominated by convection, and the temperature follows an adiabatic gradient. From thermodynamics:
where $\alpha$ is the thermal expansion coefficient, $g$ is gravitational acceleration, $T$ is absolute temperature, and $C_P$ is specific heat at constant pressure. For the upper mantle with $\alpha \approx 3 \times 10^{-5}$ K$^{-1}$,$g \approx 10$ m/s$^2$, $T \approx 1600$ K, and $C_P \approx 1200$ J/(kg$\cdot$K):
The adiabatic gradient (~0.3-0.5 K/km) is much smaller than the conductive gradient in the lithosphere (~15-25 K/km), which is why the mantle geotherm is relatively flat.
2.4 Normal Modes and Earth's Free Oscillations
Derivation 5: Eigenfrequencies of a Homogeneous Sphere
After a great earthquake, the entire Earth rings like a bell at discrete frequencies. These normal modes are standing waves described by spherical harmonics. For a homogeneous, isotropic sphere of radius $R$, the eigenfrequencies of spheroidal modes$_nS_l$ satisfy:
where $n$ is the radial order and $l$ is the angular degree. The fundamental radial mode $_0S_0$ has a period of about 20.5 minutes, corresponding to the entire Earth expanding and contracting. The football mode $_0S_2$ has a period of about 54 minutes.
Normal mode frequencies provide the most precise constraints on Earth's radial structure. The splitting of degenerate modes (due to rotation, ellipticity, and 3D heterogeneity) constrains lateral variations in velocity and density.
Hugo Benioff first observed free oscillations after the 1960 Chilean earthquake (M$_w$ 9.5), confirming theoretical predictions by Lamb (1882) and Jeans (1923). Freeman Gilbert and George Backus developed the theoretical framework for interpreting normal mode data in the 1960s, which ultimately led to the PREM model.
Toroidal and Spheroidal Modes
Normal modes are classified as either spheroidal ($_nS_l$) or toroidal ($_nT_l$). Spheroidal modes involve radial motions (compression and dilation) and are sensitive to both P-wave and S-wave velocity structure. Toroidal modes involve purely tangential motions (torsional oscillations) and are sensitive only to S-wave structure. The fundamental modes ($n = 0$) have the simplest radial structure, while higher overtones ($n > 0$) have more complex patterns with $n$ radial nodes.
The frequency of each mode depends on Earth's density and elastic structure. By measuring thousands of mode frequencies with precision of $\sim 10^{-4}$ mHz, the radial profiles of velocity and density are determined to high accuracy. Mode coupling (interaction between modes of different type and degree due to rotation and lateral heterogeneity) provides additional constraints on 3D structure.
The attenuation of normal modes, measured by the quality factor $Q$, constrains the anelastic properties of the interior. The asthenosphere has very low $Q$(~80-120), indicating significant dissipation, likely due to partial melt. The inner core has anomalously low $Q$ for shear waves (~100), which is not fully understood but may relate to grain boundary sliding or the presence of melt along grain boundaries.
2.5 Composition and Phase Transitions
The major compositional layers of Earth are constrained by matching seismic velocities and densities to laboratory measurements at high pressure and temperature. Francis Birch (1952) established that the mantle is composed of ultramafic silicates (olivine, pyroxene, garnet) while the core is dominantly iron with ~10% light elements (O, Si, S, C, H).
The 410 km and 660 km discontinuities correspond to well-characterized phase transitions in the olivine system. At 410 km (~14 GPa), olivine ($\alpha$-phase) transforms to wadsleyite ($\beta$-phase). At 520 km, wadsleyite transforms to ringwoodite ($\gamma$-phase). At 660 km (~24 GPa), ringwoodite decomposes to bridgmanite (MgSiO$_3$ perovskite) plus ferropericlase.
The 410 km transition has a positive Clapeyron slope ($dP/dT > 0$), so it occurs at shallower depth in hot regions. The 660 km transition has a negative Clapeyron slope ($dP/dT < 0$), which can impede mantle convection across this boundary. Whether mantle convection is layered or whole-mantle remains debated, though tomographic images of subducted slabs penetrating the 660 suggest at least partial whole-mantle flow.
The Post-Perovskite Phase
Murakami et al. (2004) discovered that bridgmanite (MgSiO$_3$ perovskite) transforms to a post-perovskite phase at pressures above ~125 GPa, corresponding to conditions in the D$''$ layer. This phase transition has a steep positive Clapeyron slope (~8 MPa/K), meaning it occurs at shallower depth in cold regions (like the base of subducted slabs). The double-crossing of this phase boundary by a mantle geotherm may explain seismic observations of paired discontinuities in D$''$.
Inner Core Anisotropy
Seismic waves traveling along Earth's rotation axis through the inner core arrive about 3-4 seconds faster than waves traveling in the equatorial plane. This ~3% anisotropy suggests preferred alignment of hexagonal close-packed iron crystals, possibly due to convective or solidification textures. The inner core is also heterogeneous, with the western hemisphere showing a distinct seismic signature from the eastern hemisphere, and evidence for a distinct innermost inner core with different anisotropy. The inner core is growing at a rate of ~1 mm/yr as the outer core slowly solidifies, releasing latent heat that helps power the geodynamo.
2.6 Earth's Magnetic Field and the Geodynamo
Earth's magnetic field is generated by convection of liquid iron in the outer core, acting as a self-sustaining dynamo. The field is approximately dipolar at the surface, with current dipole moment $\sim 8 \times 10^{22}$ A$\cdot$m$^2$. The magnetic Reynolds number governs whether fluid motions can sustain a magnetic field:
where $v$ is the fluid velocity, $L$ is the length scale, and $\eta_m$ is the magnetic diffusivity (~2 m$^2$/s for liquid iron). For the outer core with$v \sim 5 \times 10^{-4}$ m/s and $L \sim 2000$ km, $Rm \sim 500$, well above the critical value of ~10-50 needed for dynamo action.
The geomagnetic field reverses polarity at irregular intervals, with a mean reversal rate of ~4-5 per Myr during the current epoch. During a reversal, the dipole field weakens and the non-dipole components become relatively stronger. The process takes ~1000-10,000 years. Long intervals without reversals are called superchrons: the Cretaceous Normal Superchron lasted from 124-84 Ma (~40 Myr without reversal).
Joseph Larmor (1919) first proposed the dynamo mechanism. Walter Elsasser (1946) and Edward Bullard (1949) developed the mathematical theory. Gary Glatzmaier and Paul Roberts (1995) produced the first self-consistent numerical geodynamo simulation that exhibited spontaneous reversals.
Computational Lab: Earth's Interior
PREM Model, Geotherms, and Seismic Discontinuities
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Phase Transitions and Mineral Physics at High Pressure
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